a) Define typical polyfunctional acid ?

b) Show the equations of dissociation mechanism of phosphoric acid as an example.

c) Write the equation for calculating the [H3O*].​

Answers

Answer 1

a) A polyfunctional acid is an acid that has more than one functional group.

b) The equations of dissociation of phosphoric acid are:    

H₃PO₄ + H₂O ⇄ H₂PO₄⁻ + H₃O⁺   H₂PO₄⁻ + H₂O ⇄ HPO₄²⁻ + H₃O⁺  HPO₄²⁻ + H₂O ⇄ PO₄³⁻ + H₃O⁺  

c) The equation for calculating the concentration of H₃O⁺ is [tex] [H_{3}O^{+}] = (\frac{K_{1}K_{2}K_{3}[H_{3}PO_{4}]}{[PO_{4}^{-3}]})^{1/3} [/tex]

       

a) A polyfunctional acid can be defined as an acid that has more than one functional group. Phosphoric acid (H₃PO₄) is an example of polyfunctional acid since it is composed of three hydroxyl groups joined to a phosphorus atom, which is also joined to an oxygen atom by a double bound. In that structure, the three hydrogen atoms of the hydroxyl groups give the acidic behavior to this compound.                  

b) Phosphoric acid has three equations of dissociation:  

H₃PO₄ + H₂O ⇄ H₂PO₄⁻ + H₃O⁺    (1)H₂PO₄⁻ + H₂O ⇄ HPO₄²⁻ + H₃O⁺   (2)HPO₄²⁻ + H₂O ⇄ PO₄³⁻ + H₃O⁺   (3)  

The dissociation constants for the three above equations are:

[tex] K_{1} = \frac{[H_{2}PO_{4}^{-}][H_{3}O^{+}]}{[H_{3}PO_{4}]} [/tex]   (4)

[tex] K_{2} = \frac{[HPO_{4}^{2-}][H_{3}O^{+}]}{[H_{2}PO_{4}^{-}]} [/tex]    (5)

[tex] K_{3} = \frac{[PO_{4}^{3-}][H_{3}O^{+}]}{[HPO_{4}^{2-}]} [/tex]    (6)

c) We can calculate the concentration of H₃O⁺ for each equilibrium with the equations (4), (5), and (6).    

The general reaction of dissociation of phosphoric acid is given by the sum of equations (1), (2), and (3):

H₃PO₄ + 3H₂O ⇄ PO₄³⁻ + 3H₃O⁺   (7)  

The concentration of H₃O⁺ for the total dissociation reaction (eq 7) can be found as follows:  

[tex] K_{t} = \frac{[PO_{4}^{-3}][H_{3}O^{+}]^{3}}{[H_{3}PO_{4}]} [/tex]   (8)

Where:

[tex] K_{t} = K_{1}*K_{2}*K_{3} [/tex]

Hence, by knowing the dissociation constants K₁, K₂ and K₃, and the concentrations of PO₄³⁻ and H₃PO₄, the [H₃O⁺] is:

[tex][H_{3}O^{+}] = (\frac{K_{1}K_{2}K_{3}[H_{3}PO_{4}]}{[PO_{4}^{-3}]})^{1/3}[/tex]

         

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Related Questions

Which of the following represents a physical change?

Answers

Answer:

» Water evaporating to gas.

» Solid subliming to gas.

» Water freezing to solid.

» Solid melting to liquid.

Explanation:

[tex]{ \underline{ \blue{ \sf{christ \:† \: alone }}}}[/tex]

Someone help please I don’t know the answer to the question I meeed help

Answers

Answer: 143.3  

137+115+104+263+98 divided by 5.Which gives us 143.3

Which side of the chain should you count from when naming organic compounds?
Center
Right side
Left side
Side that will give you the longest Carbon chain

Answers

Side that will give you the longest carbon chain will be counted when naming organic compounds.

What is an Organic compound?

These are chemical compounds that contain carbon-hydrogen or carbon-carbon bonds in their structure.

The longest carbon chain should be counted first to ascertain the type of compound to be named.

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18. What is the density of a substance with a mass of 0.90 kg and a volume of 1.2 mL?
21. An oxygen tank in the lab has a pressure of 12 atm at 250C. If the pressure inside the gas tank exceeds 25 atm, the tank will explode. If a fire occurs in the lab, raising the temperature of the gas inside the cylinder to 398oC, will the tank explode?

Answers

Answer:

fffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffffff

Explanation:

I 100 mL o a pharmaceutical preparation contains 20 mL o a 50% w/v solution o benzalkonium chloride, what is the percent strength o that agent in the solution

Answers

The percentage strength of the agent is 10 %

Since 100 mL of a pharmaceutical preparation contains 20 mL of a 50% w/v solution of benzalkonium chloride, we desire to find the percentage strength of that agent in the 100 mL solution.

Let C₁ = percentage strength of 20 mL solution = 50 %, V₁ = initial volume = 20 mL, C₂ = percentage strength of agent in 100 mL solution and V₂ = final volume = 100 mL.

Since the initial quantity of agent in 20 mL solution equals the final quantity of agent in 100 mL solution, we have that

C₁V₁ = C₂V₂

So, making C₂ = percentage strength of agent in 100 mL solution the subject of the formula, we have

C₂ = C₁V₁/V₂

Substituting the values of the variables into the equation, we have

C₂ = C₁V₁/V₂

C₂ = 50 % × 20 mL/100 mL

C₂ = 50 % × 0.2

C₂ = 10 %

So, the percentage strength of the agent is 10 %.

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Why benzene is called aromatic compound according to Huckel’s rule?​

Answers

Answer:

It obeys rule

Explanation:

Benzene is an aromatic hydrocarbon because it obeys Hückel's rule.

Answer:

Benzene is an aromatic compound because it is planar, cyclic, conjugated and has (4n +2) π electrons, where n= 1.

Explanation:

Hückel's rule states that a molecule is aromatic if it is planar, cyclic, conjugated and has (4n +2) π electrons.

Breaking it down into 4 requirements, we have:

planarcyclicconjugated(4n +2) π electrons

Let's look at each of the 4 parts!

What is planar?

Planar refers to the molecule being flat. When an atom is sp² hybridized, it is in a trigonal planar geometry. Let's look at the benzene molecule. Each carbon is attached to 3 other atoms, namely 2 carbons and 1 hydrogen. This means that each carbon is sp² hybridized, making the molecule planar.

Cyclic

This refers to the molecule having a closed ring shape. Benzene fulfils this criteria.

Conjugation

This refers to a system of connected p orbitals, which allows π electrons to delocalize. Each carbon atom in benzene has one 2p orbital, making benzene a conjugated molecule. For molecules that are not cations or anions, conjugated molecules are those that have alternating single and double bonds.

(4n +2) π electrons

n is an integer (e.g. 0, 1, 2, 3) thus for the molecule to be aromatic, it can have 2, 6 or 10 π electrons (non exhaustive). This separates an aromatic compound from an antiaromatic compound, which has 4n π electrons instead.

Benzene has 6 π electrons, so n has a value of 1 in this case.

Thus, benzene is an aromatic compound because it is planar, cyclic, conjugated and has (4n +2) π electrons.

_______

Counting the number of π electrons

Let's look at π bonds!

A double bond is made up of 1 σ bond and 1 π bond, and each π bond is made up of 2 π electrons. We do not count the number of single bonds since single bonds are made up of 1 σ bond only.

There are 3 double bonds in the Kekulé structure of benzene. Thus, the number of π electrons in benzene is 3(2)= 6.

Attached diagrams

Kekulé structure of benzenesp² hybridized carbon6 p orbitals in benzene ring

help me in my hw,wt is physical change and chemical change Answer it asap plz don't spam​

Answers

Answer:

Sorry but i don't undertsnad the question.

Explanation:

Answer:

A physical change is a change to the physical—as opposed to chemical—properties of a substance. They are usually reversible. The physical properties of a substance include such characteristics as shape, color, texture, flexibility, density, and mass.

A chemical change happens when one chemical substance is transformed into one or more different substances, such as when iron becomes rust.

Do u want examples ?

How would you expect cesium, Cs, to react with water? explaining your reasoning.

Answers

Answer:

Caesium reacts rapidly with water to form a colourless basic solution of caesium hydroxide (CsOH) and hydrogen gas (H2).

Explanation:

The reaction continues even when the solution becomes basic. The resulting solution is basic because of the dissolved hydroxide. The reaction is exothermic.

Draw all four products when the following compound undergoes dehydrohalogenation and rank them in terms of stability. Which product do you expect to be the major product?

Answers

Answer:

2 Methyl pent 2 ene

what is the bond energy required to break one mole of carbon-carbon bonds​

Answers

Answer:

100 kcal of bond energy

Which phenomenon explained below is an example of deposition?
Select the correct answer below:

A) Hail is formed from water droplets lifted by air currents to an altitude where they turn into pellets of ice.

B) Frost forms when cold evening temperatures convert the humidity in the air to thin layers of ice on the ground.

C) In the winter, the top few inches of a pond turn to ice.

D) The visible cloud arising from a boiling tea kettle is not actually steam, but droplets of liquid water that form as the
steam cools in the air.

Answers

Answer:

b

Explanation:

deposition is when water turns from gas to solid. b is the only one that fits

Deposition is frost forms when cold evening temperatures convert the humidity in the air to thin layers of ice on the ground.

What is deposition?

Deposition is a process that involves collection of large mass or when mean distance between molecules are reduced. It can also be explained as gathering of substances together to form a larger mass.

Therefore, the phenomenon explained in the given example about deposition is frost forms when cold evening temperatures convert the humidity in the air to thin layers of ice on the ground.

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What will be the new volume if the temperature remain constant ? The pressure on 2.50L of anaesthetic gas is change from 760mm Hg to 304mm Hg.​

Answers

Answer:

[tex]\boxed {\boxed {\sf 6.25 \ L}}[/tex]

Explanation:

We are asked to find the new volume given a change in pressure. Since the temperature remains constant we are only concerned with volume and pressure. We will use Boyle's Law, which states the volume of a gas is inversely proportional to the pressure. The formula for this law is:

[tex]P_1V_1= P_2V_2[/tex]

Initially, the volume of the gas is 2.50 liters and the pressure is 760 millimeters of mercury.

[tex]760 \ mm \ Hg * 2.50 \ L = P_2V_2[/tex]

The pressure is changed to 304 millimeters of mercury, but the volume is unknown.

[tex]760 \ mm \ Hg * 2.50 \ L = 304 \ mm \ Hg * V_2[/tex]

We are solving for the new volume so we must isolate the variable V₂. It is being multiplied by 304 millimeters of mercury. The inverse operation of multiplication is division. Divide both sides by 304 mm Hg.

[tex]\frac {760 \ mm \ Hg * 2.50 \ L }{304 \ mm \ Hg}= \frac{304 \ mm \ Hg * V_2}{304 \ mm \ Hg}[/tex]

[tex]\frac {760 \ mm \ Hg * 2.50 \ L }{304 \ mm \ Hg}= V_2[/tex]

The units of millimeters of mercury cancel out.

[tex]\frac {760 * 2.50 \ L }{304 }= V_2[/tex]

[tex]\frac {1900}{304} \ L =V_2[/tex]

[tex]6.25 \ L =V_2[/tex]

The new volume of the anesthetic gas after the change in pressure is 6.25 liters.

what is the zeff of carbon​

Answers

Answer:

Explanation:

The steps to calculate the Zeff is :

1)  Write  the electronic configuration.

Carbon: 1s2 2s2 2p2

Oxygen: 1s2 2s2 2p4

2) there are two core electrons in each atom and four in carbon and six in oxygen.

1s) (2s2p)

3) as mentioned the shielding of electrons within the same shell is negligible.

4) for electron of s or p orbital  the shielding contribution by the electrons having a principal quantum number less by one would be 0.85 each. And all electrons further left would contribute an amount of 1.0 each.

5) For oxygen:

Zeff = Z - S

S = 2X0.85 = 1.7

Zeff = 8- 1.7 = 6.3

For carbon

Zeff = Z - S

S = 2X0.85 = 1.7

Zeff = 6- 1.7 = 4.3

9.7300x10^2 + 9.8700x10^3

? × 10^?

Answers

Answer:

19.6 x 10⁵

1.96 x 10⁶

I hope it's helps you

Explain why it is not advisable to add water to acid when
mixing them​

Answers

Answer:

Consequence

you form an extremely concentrated solution of acid initially.and the solution may boil very violently, splashing concentrated acid.  I hope this helped! :)

Để xác định hàm lượng Cu trong hợp kim Cu-Zn người ta làm như sau: Hòa
tan hoàn toàn 2,068g mẫu hợp kim Cu-Zn trong lượng dư axit HNO3, thu được dung
dịch X. Đun đuổi axit dư, điều chỉnh tới pH 3 thu được 100mL dung dịch Y. Lấy
10mL dung dịch Y, thêm KI dư, rồi chuẩn độ dung dịch tạo thành bằng dung dịch
Na2S2O3 0,1M thì thấy hết 15,0 mL. Viết các phương trình phản ứng xảy ra. Tính
hàm lượng Cu trong mẫu hợp kim trên.

Answers

Answer: yes 1+1






Explain:

What volume of 6.9 M NaOH is needed to completely titrate 0.42 L of 2.39 M phosphoric acid according to
the equation:

H3PO4(aq) + 3NaOH(aq) + Na3PO4(aq) + 3H2O(aq)

A) O 0.05 L
B) O6.93 L
C) O0.44 L
D) 03.01 L
E) 436.43 L

Answers

Taking into account the definition of molarity and the stoichiometry of the reaction, the correct option is option C) 0.44 L of 6.9 M NaOH is needed to completely titrate 0.42 L of 2.39 M phosphoric acid.

The balanced reaction is:

H₃PO₄ (aq) + 3 NaOH (aq) → Na₃PO₄ (aq) + 3 H₂O(aq)

Then, by stoichiometry of the reaction (that is, the relationship between the amount of reagents and products in a chemical reaction), the following amounts of moles of each compound participate in the reaction:

H₃PO₄: 1 mole NaOH: 3 moles Na₃PO₄: 1 mole H₂O: 3 moles

Molarity is the number of moles of solute that are dissolved in a given volume.

Molarity is determined by:

[tex]Molarity=\frac{number of moles of solute}{volume}[/tex]

 Molarity is expressed in units [tex]\frac{moles}{liter}[/tex].

In this case, 0.42 L of 2.39 M phosphoric acid reacts. So, by definition of molarity, the number of moles that participate in the reaction is calculated as:

[tex]2.39 \frac{moles}{liter}=\frac{number of moles of phosphiric acid}{0.42 liters}[/tex]

Solving:

number of moles of phosphiric acid= 2.39 [tex]\frac{moles}{liter}[/tex]* 0.42 liters

number of moles of phosphiric acid= 1.0038 moles ≅ 1 mole

Approaching 1 mole of the amount of phosphoric acid required, then by stoichiometry of the reaction, 3 moles of NaOH are necessary to react with 1 mole of the acid.

Then by definition of molarity and knowing that 6.9 M NaOH is needed, you can calculate the necessary volume amount of NaOH by:

[tex]6.9 \frac{moles}{liter} =\frac{3 moles}{volume}[/tex]

Solving:

6.9 [tex]\frac{moles}{liter}[/tex]* volume= 3 moles

[tex]volume=\frac{3 moles}{6.9\frac{moles}{liter} }[/tex]

volume= 0.44 L

The correct option is option C) 0.44 L of 6.9 M NaOH is needed to completely titrate 0.42 L of 2.39 M phosphoric acid.

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An ion of a single pure element always has an oxidation number of ________.

A. None of these
B. magnitude equal to its atomic number
C. 1
D. 0

Answers

Answer:

0

Explanation:

pure elements will always possess an oxidation number of 0, regardless of their charge.

Answer:

D.) 0

Explanation:

I got it correct on founders edtell

If sodium chloride (NaCl) is dissolved in water, how will the vapor pressure of the water be affected?

A. The vapor pressure will be raised, making it more easier to boil.
B. The vapor pressure will be raised, making it more difficult to boil.
C. The vapor pressure will be lowered, making it easier to boil.
D. The vapor pressure will be lowered, making it more difficult to boil.

Answers

D. The vapor pressure will be lowered, making it more difficult to boil.

Adding salt to water makes increases the boiling point, because there are more intermolecular forces to overcome since some of the water molecules interact with the salt ions.

The vapor pressure will be lowered, making it more difficult to boil If sodium chloride (NaCl) is dissolved in water. Hence, option D is correct.

What is vapor pressure?

It can be defined as the pressure exerted by a vapor with its condensed phases in a closed system at a given temperature show the equilibrium vapor is a well-known measure of a liquid evaporation rate.

The vapor pressure of a liquid is the point at which equilibrium pressure is reached in a closed container. The  molecules leaving the liquid and going into the gaseous phase and molecules leaving the gaseous phase and entering the liquid phase.

It is measured in the standard units of pressure the international system of units. Pressure as a derived unit with the dimension of force per area and designate the Pascal (Pa) as its standard unit.

When common salt is dissolved in water boiling point of a solution increases the boiling point of a substance is the temperature at which it will be lowered, making it more difficult to boil If sodium chloride (NaCl) is dissolved in water. Hence, option D is correct.

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If the starting material has no stereogenic centers, when carbonyl compounds are reduced with a reagent such as LiAlH4 or NaBH4 and a new stereogenic center is formed, what will the composition of the product mixture be?
A) Forms a racemic mixture of the two possible enantiomers.
B) Forms more of one enantiomer than another because of steric reasons around the carbonyl.
C) Forms more of one enantiomer than another depending on the temperature of the reaction.
D) Forms different products depending on the solvent used.

Answers

Answer:

A) Forms a racemic mixture of the two possible enantiomers

When carbonyl compounds are reduced with a reagent such as LiAlH₄ or NaBH₄ and  new stereogenic center is formed chemical change will lead to products that form a racemic mixture of the two possible enantiomers.

What is a chemical change?

Chemical changes are defined as changes which occur when a substance combines with another substance to form a new substance.Alternatively, when a substance breaks down or decomposes to give new substances it is also considered to be a chemical change.

There are several characteristics of chemical changes like change in color, change in state , change in odor and change in composition . During chemical change there is also formation of precipitate an insoluble mass of substance or even evolution of gases.

There are three types of chemical changes:

1) inorganic changes

2)organic changes

3) biochemical changes

During chemical changes atoms are rearranged and changes are accompanied by an energy change as new substances are formed.

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Could someone help with this? Much appreciated!

Answers

Answer:

The 3rd answer down.

Na²O (sodium oxide) will be a base when exposed to water H²O

Explanation:

Sodium Oxide Na²O, will become Sodium Hydroxide after being exposed to water (at 80% I believe).

The oxygen ion in Na²O has 2 extra electrons which makes it highly charged and very attractive to hydrogen ions. The attraction is so strong that when Na²O comes in contact with H²O, the O(-2) strips off a hydrogen from water, forming 2 x OH ions which of course are still strongly basic.

The following two compounds each exhibit two heteroatoms (one nitrogen atom and one oxygen atom). In compound A, the lone pair on the nitrogen atom is more likely to function as a base. However, in compound B, the lone pair on the oxygen atom is more likely to function as a base. Explain this difference by selecting the correct reason(s)

Answers

Answer:

The answer is the photo attached

Explanation:

What mass of water is formed in the reaction of 4.16g H with excess oxygen gas.

Answers

Answer:

Explanation:

Start with a balanced equation.

2H2 + O2 → 2H2O

Calculate mole H2 using the formula: n = m/M, where:

n = mole

m = mass (g)

M = molar mass (g/mol)

Calculate molar mass of H2.

M H2 = 2 × 1.008 g/mol = 2.016 g/mol

Calculate moles H2.

n H2 = 4.16 g H2/2.016 g/mol = 2.063 mol H2

Calculate moles H2O by multiplying moles H2 by the mole ratio between H2O and H2 from the balanced equation, so that moles H2 cancel.

2.063 mol H2 × (2 mol H2O/2 mol H2) = 2.063 mol H2O

The mass of water will be calculated by rearranging the n = m/M formula to isolate m;

m = n × M

Calculate the molar mass H2O.

M H2O = (2 × 1.008 g/mol) + (1 × 15.999 g/mol) = 18.015 g/mol

Calculate the mass H2O.

m = n × M = 2.063 mol H2O × 18.015 g/mol = 37.2 g H2O

4.16 g H2 with excess O2 will produce 37.2 g H2O.

A sample of water at 21.5°C required an input of 1.69 x 104 of heat to reach its boiling point, 100.0 °C. What was the mass of the
water?

Answers

Fawn spends hours each week managing employee shifts and schedules, time she should be spending on other restaurant operations. What can she do? O a) Start leaving more time in her week for scheduling-related tasks b) Write everything down in a weekly planner O c) Consider online inventory management software O d) Consider online scheduling software

The sugars can be classified as either aldoses or ketoses.

a. True
b. Fasle

Answers

It is True :) have a good day
the answer is a.) true :)

What is the maximum number of electrons in the following energy level?
n = 4

Answers

Answer: 32 electrons

Explanation:

What is Entropy?

A. The opposite of Enthalpy
B. The temperature at which a reaction is feasible.
C. A measure of disorder.
D. Free energy used for a reaction.

Answers

Answer:

C. A measure of disorder :)

A(n) _____, used as part of the stationary phase, has an affinity for the solvent and the chemical components of the mixture. adsorbent eluent Rf factor chromatogram

Answers

The Adsorbent is used as part of the stationary phase and has an affinity for the solvent and the chemical components of the mixture.

The adsorbent has a high affinity for solvent and the chemical components of the mixture.

Chromatography is a method of separation in which the mixture of substances is introduced into a mobile phase (solvent). The separation occurs as the solvent interacts with an adsorbent(stationary phase).

The extent of separation of the components of the mixture depends on the extent of interaction between the mobile and the stationary phase . This interaction also determines the retention factor (Rf) of the separation.

For a definition of chromatography, see

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Chad drew a diagram to compare animal cells and bacterial cells.

Which label belongs in the area marked X?

Answers

Explanation:

Don't know wwwwmkbnkkkoo

a=bcd in order to solve the equation above for b you must multiply both sides of the equation by the same expression
a x _ = bcd x _
the results equation is:
b=

Answers

Both sides of the equation must be multiplied by 1/cd to give the following equation: b = a/cd

The following equation was given in this question: a = bcd. This means that a = b × c × d.

Hence, to make "b" the subject of the formula, we have to eliminate "cd" from the side of the equation with "b". To do that, we multiply both sides of the equation with the same expression as follows:

a x 1/cd = bcd x 1/cd

"cd" cancels out "cd" in the right side of the equation to result to:

a/cd = b

Therefore, b = a/cd

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