The rate constant of an SN1 reaction depends on the nucleophile b. The rate constant of an SN2 reaction does not depend on the nucleophile c. SN1 reactions proceed via carbocation intermediates d. The SN2 mechanism does not involve an intermediate

Answers

Answer 1

Answer:

The rate constant of an SN1 reaction depends on the nucleophile

The rate constant of an SN2 reaction does not depend on the nucleophile

Explanation:

Let us recall that in an SN1 reaction, the rate determining step involves only the alkyl halide substrate and not the nucleophile. Hence;

Rate = k[RX]

Therefore;

k= Rate/[RX]

For an SN2 reaction, the rate determining step involves both the nucleophile and the alkyl halide substrate.

Hence;

Rate = k[Nu-] [RX]

k= Rate/[Nu-] [RX]

Note that;

[Nu-] = concentration of the nucleophile

[RX] =concentration of alkyl halide substrate

k= rate constant

We can see from the above derivations that;

1) The rate constant of an SN1 reaction does not depend on the nucleophile

2) The rate constant of an SN2 reaction depends on the nucleophile

The Rate Constant Of An SN1 Reaction Depends On The Nucleophile B. The Rate Constant Of An SN2 Reaction

Related Questions

Oxygen is composed of three isotopes: oxygen-16, oxygen-17 and oxygen-18 and has an average atomic mass of 15.9982 amu. Oxygen-17 has a mass of 16.988 amu and makes up 0.032% of oxygen. Oxygen-16 has a mass of 15.972 amu and oxygen-18 has a mass of 17.970 amu. What is the percent abundance of oxygen-18?

Answers

Answer:

The percent abundance of oxygen-18 is 1.9066%.

Explanation:

The average atomic mass of oxygen is given by:

[tex] m_{O} = m_{^{16}O}*\%_{16} + m_{^{17}O}*\%_{17} + m_{^{18}O}*\%_{18} [/tex]

Where:

m: is the atomic mass

%: is the percent abundance

Since the sum of the percent abundance of oxygen isotopes must be equal to 1, we have:  

[tex] 1 = \%_{16} + \%_{17} + \%_{18} [/tex]

[tex] 1 = x + 3.2 \cdot 10^{-4} + \%_{18} [/tex]

[tex] \%_{18} = 1 - x - 3.2 \cdot 10^{-4} [/tex]

Hence, the percent abundance of O-18 is:  

[tex] m_{O} = m_{^{16}O}*\%_{16} + m_{^{17}O}*\%_{17} + m_{^{18}O}*\%_{18} [/tex]  

[tex]15.9982 = 15.972*x + 16.988*3.2 \cdot 10^{-4} + 17.970*(1 - 3.2 \cdot 10^{-4} - x)[/tex]

[tex] x = 0.980614 \times 100 = 98.0614 \% [/tex]                                                              

Hence, the percent abundance of oxygen-18 is:

[tex]\%_{18} = (1 - 3.2 \cdot 10^{-4} - 0.980614) \times 100 = 1.9066 \%[/tex]                      

Therefore, the percent abundance of oxygen-18 is 1.9066%.

I hope it helps you!                                                      

A sample of aluminum, which has a specific heat capacity of , is put into a calorimeter (see sketch at right) that contains of water. The temperature of the water starts off at . When the temperature of the water stops changing it's . The pressure remains constant at .Calculate the initial temperature of the aluminum sample. Be sure your answer is rounded to significant digits.

Answers

Complete Question

A sample of aluminum, which has a specific heat capacity of 0.897 JB loc ! is put into a calorimeter (see sketch at right) that contains 200.0 g of water. The aluminum sample starts off at 85.6 °C and the temperature of the water starts off at 16.0 °C. When the temperature of the water stops changing it's 20.1 °C. The pressure remains constant at 1 atm. Calculate the mass of the aluminum sample.

Answer:

[tex]M=58g[/tex]

Explanation:

From the question we are told that:

Heat Capacity [tex]H=0.897[/tex]

Mass of water [tex]M=200g[/tex]

Initial Temperature of Aluminium [tex]T_a=85.6[/tex]

Initial Temperature of Water [tex]T_{w1}=16.0[/tex]

Final Temperature of Water  [tex]T_{w2}=16.0[/tex]

Generally

Heat loss=Heat Gain

Therefore

[tex]M*0.897*(85.6-20.1) =200*4.184*(20.1-16)[/tex]

[tex]M=58g[/tex]

A reaction vessel for synthesizing ammonia by reacting nitrogen and hydrogen is charged with 6.54 kg of H2 and excess N2. A total of 30.4 kg of NH3 are produced. What is the percent yield of the reaction

Answers

Explanation:

The given data is:

The mass of hydrogen is 6.54 kg.

The actual yield is 30.4 kg.

The balanced chemical equation of the reaction is:

[tex]N_2(g)+3H_2(g)<=>2NH_3(g)[/tex]

At first the theoretical yield should be calculated by using the balanced chemical equation:

3 mol. of hydrogen forms ---- 2 mol. of ammonia.

The molar mass of hydrogen is 2.0 g/mol.

The molar mass of ammonia is 17.0 g/mol.

Hence, the above statement can be rewritten as:

6g of hydrogen forms --- 34g of ammonia.

Then,

6.54g of hydrogen forms :

[tex]6.54 kg x 34 g / 6 g\\=37.1 kg[/tex]

% yield = (actual yield /theoretical yield )x 100

=(30.4 kg /37.1 kg )x100

=81.9

Hence, % yield is 81.9.

If a hydrogen of an alkane is replaced by NH, the compound becomes_________

a. alcohol

b. carboxylic acid

c. phenol

d. amine​

Answers

Answer:

d. amine.

It becomes an amine.

Explanation:

With general formular

[tex]{ \bf{primary \: amine :R - NH _{2}}} \\ { \bf{secondary \: amine : R {}^{i} - NH - R}} \\ { \bf{tertiary \: amine :R {}^{ii} - N(R {}^{i} ) - R }}[/tex]

R is the aryl group such as alkane

i think it becomes an amine

(d) 40g of sulphur
Calculate the number of moles of 40g of sulphur

Answers

Answer:

It is 1.25 moles

Explanation:

Molar mass of sulphur = 32 g

[tex]{ \bf{moles = \frac{given \: mass}{molar \: mass} }} [/tex]

Substitute:

[tex]{ \sf{moles = \frac{40}{32} }} \\ { \sf{ = 1.25 \: moles}}[/tex]

Based on the standard EMF series and your knowledge of half-reactions, determine the cell potential and spontanei ty of a cell that consists of a pure cobalt electrode in a solution of Co^2+ ions; the other half is a lead electrode immersed in a Pb^2+ solution.
Pb +2e- Pb Sn +2e Sn Ni 2e Ni Co 2e -0.126 -0.136 -0.250 -0.277 Co
a. +0.403, spontaneous
b. -0.403, nonspontaneous
c. +0.151, spontaneous
d. -0.151, nonspontaneous

Answers

Answer:

+0.151, spontaneous

Explanation:

Given that;

Co^2+(aq) + 2e ---->Co(s) -0.28 V

Pb^2+(aq) + 2e ---->Pb(s). -0.13 V

Hence Co is the anode and Pb is the cathode

E°cell = E°cathode - E°anode

So;

E°cell = -0.13 V - (-0.28 V)

E°cell = 0.15 V

The cell reaction is spontaneous since E°cell is positive.

Based on the following observations decide the order of reactivity for hydrogen, magnesium, and copper. Hydrochloric acid reacts with magnesium but did not react with copper. magnesium reacted with copper sulfate. Write your answers in the blanks. For magnesium write magnesium for hydrochloric acid write hydrogen and for copper sulfate write copper.

Answers

Answer:

Mg> H> Cu

Explanation:

We can see from the question that hydrochloric acid reacted with magnesium as follows;

Mg(s) + 2HCl(aq) ----> MgCl2(aq) + H2(g)

Copper does not react with HCl which means that copper is less reactive than hydrogen hence it can not displace hydrogen from a dilute acid solution.

The order of reactivity of the elements then is ; Mg> H> Cu

A 10.00 mL sample of ethanol is added to 250.0 mL of water in order to observe the freezing point depression of the water. Consider the possible errors in this experiment, and determine whether each would cause the freezing point of the water to increase, decrease, or remain the same compared with the expected results. The ethanol sample is left out for several minutes before being added to the water, allowing a Choose... significant amount to evaporate. Some of the water is splashed out of the container before the ethanol is added. Choose... Choose... Instead of starting the experiment with room temperature water, the experiment is started with cold water. It is discovered that the 10.00 g ethanol sample is actually 95% ethanol and 5% water. Choose... Choose... Some of the ethanol and water solution is spilled out of the container during temperature measurement

Answers

Answer:

b

Explanation:

Addition of a solute lowers the freezing point of a substance.

Let us recall that the addition of a solute to a solution lowers the freezing point of the pure solution. This is because, freezing point depression is a colligative property. It depends on the number of solute molecules present.

The following are possible errors in the experiment:

The ethanol sample is left out for several minutes before being added to the water allowing a significant amount to evaporate. This causes the freezing point of water to increase compared with the expected results.Some of the water is splashed out of the container before the ethanol is added. This causes the freezing point of water to increase compared with the expected results. It is discovered that the 10.00 g ethanol sample is actually 95% ethanol and 5% water. This causes the freezing point of water to decrease compared with the expected results.Some of the ethanol and water solution is spilled out of the container during temperature measurement. This causes the freezing point of water to remain the same compared with the expected results.

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Which redox reaction would most likely occur if zinc and copper metal were
added to a solution that contained zinc and copper ions?
Click for a reduction potential chart
A. Cu + Zn → Cu2+ + Zn2+
B. Cu + Zn2+
Cu2+ + Zn
C. Cu2+ + Zn → Cu + Zn2+
D. Cu2+ + Zn2+ → Cu + Zn

Answers

Answer:

C

Explanation:

b/c when copper and zinc metal are addedto solution,then the solution will be consider under redox reaction

[tex]Cu^{2+} + Zn[/tex] → [tex]Cu + Zn^{2+}[/tex] is the redox reaction. Hence, option C is correct.

What is Redox Reaction?

A chemical reaction taking place between an oxidizing substance and a reducing substance.

The oxidizing substance is used to lose electrons in the reaction, and the reducing substance is used to gain electrons.

On the reduction potential chart, zinc is a stronger oxidizing agent than, Copper (Cu), which is a reducing agent as compared to silver

The redox reaction most likely occurs if silver and copper metal were added to a solution that contained silver and copper ions is ;

[tex]Cu^{2+} + Zn[/tex] → [tex]Cu + Zn^{2+}[/tex]

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Calculate the mass of isoborneol in 2.5 mmol of isoborneol and the theoretical yield (in grams) of camphor from that amount of isoborneol
isoborneol = 154.25 g mol?1
Camphor, Molar mass = 152.23 g/mol

Answers

Answer:

[tex]m_{isoborneol }=0.39g\\\\m_{Camphor}=0.38g\\[/tex]

Explanation:

Hello there!

In this case, according to the given information, it turns out possible for us to infer that the reaction whereby isoborneol goes to camphor occurs in a 1:1 mole ratio, that is why the theoretical yield of the latter is also 2.5 mmol (0.0025 mol) but the masses can be calculated as follows:

[tex]m_{isoborneol }=0.0025mol*\frac{154.25g}{1mol} =0.39g\\\\m_{Camphor}=0.0025mol*\frac{152.23 g}{1mol} =0.38g\\[/tex]

Because of the fact this is a rearrangement reaction whereas the number of atoms is not significantly modified.

Regards!

What trends were seen in medeleevs periodic table

Answers

Answer:

groups are based on how many electrons to become stable

Explanation:

14. What is the oxidation number of oxygen in HSO4 -

Answers

Answer:

2

Explanation:

i did this

Which substance would be the most soluble in gasoline?
Select one:
A. hexane
B. NaNO3
C. HCI
D. water
E. Nacl

Answers

I think the answer most be d

In chemistry like dissolves like hence hexane will dissolve in gasoline.

Dissolution stems from intermolecular interaction between solute and solvent molecules.

If this interaction can not occur, dissolution of one substance in another is impossible.

Hexane dissolves in gasoline because the both substances are non-polar and can interact with each other effectively.

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An important difference between fuel cells and batteries is that batteries _______. Select the correct answer below: do not require a continuous source of fuel require a continuous source of fuel are able to expel products are constantly resupplied with reactants

Answers

Answer: the correct option is that batteries (do NOT require a continuous source of fuel).

Explanation:

A battery can be classified as an electrochemical cell that has the ability to produce electric current. They do NOT require a continuous supply of fuel because it contains all the reactants needed to produce electricity. Below are some examples of batteries that are commonly used:

--> Primary battery: This is a single use battery because it can't be recharged. A typical example is the dry cell.

--> Secondary battery: This type of battery can be recharged. They are used as a power source for smartphones, electronic tablets, and automobiles.

A FUEL CELL is known as a device that converts chemical energy into electrical energy. Fuel cells are similar to batteries but require a continuous source of fuel, often hydrogen. They will continue to produce electricity as long as they are constantly resupplied with reactants. Hydrogen fuel cells have been used to supply power for satellites, space capsules, automobiles, boats, and submarines.

Answer:

accumulate reaction byproducts

Explanation:

Batteries accumulate reaction byproducts.  Fuel cells are similar to batteries but require a continuous source of fuel, often hydrogen. They will continue to produce electricity as long as fuel is available. Hydrogen fuel cells have been used to supply power for satellites, space capsules, automobiles, boats, and submarines.  A battery is an electrochemical cell or series of cells that produces an electric current.

Nitric acid and nitrogen monoxide react to form nitrogen dioxide and water, like this: At a certain temperature, a chemist finds that a 7.7 L reaction vessel containing a mixture of nitric acid, nitrogen monoxide, nitrogen dioxide, and water at equilibrium has the following composition: compound amount
HNO 16.2 g 11.0 g 18.6 g H20 236.7 g 3 NO NO
Calculate the value of the equilibrium constant K for this reaction. Round your answer to 2 significant digits.

Answers

Answer:

K = 3.3

Explanation:

Nitric acid, HNO3, reacts with nitrogen monoxide, NO, to produce nitrogen dioxide, NO2 and water H2O as follows:

2HNO3(g) + NO(g) → 3NO2(g) + H2O(g)

Where equilibrium constant, K, is:

K = [NO2]³[H2O] / [HNO3]²[NO]

[] is the molar concentration of each species at equilibrium.

To solve this question we need to find molarity of each gas and replace these in the equation as follows:

[NO2] -Molar mass NO2-46.0g/mol-

18.6g * (1mol/46.0g) = 0.404mol / 7.7L = 0.0525M

[H2O] -Molar mass:18.01g/mol-

236.7g * (1mol/18.01g) = 13.14 moles / 7.7L = 1.707M

[HNO3] -Molar mass:53.01g/mol-

16.2g * (1mol/53.01g) = 0.3056 moles / 7.7L = 0.0397M

[NO] -Molar mass: 30.0g/mol-

11.0g * (1mol/30.0g) = 0.367 moles / 7.7L = 0.0476M

Replacing:

K = [NO2]³[H2O] / [HNO3]²[NO]

K = [0.0525M]³[1.707M] / [0.0397M]²[0.0476M]

K = 3.3

the ability for carbon to form long chain or rings is

Answers

califactual. thsi is correct bcuz carbon takes 20 minutes to dissolve and ring making it a factual

2. Calculate the wavelength of the emitted photon from hydrogen for the transition from ni = 3 to nf = 2. What part of the visible spectrum is this wavelength? Visible wavelengths are: Red  700 - 620 nm, Yellow  620 - 560 nm, Green  560 - 500 nm, Blue 500 - 440 nm, and Violet  440 - 400 nm.

Answers

Answer:

The correct answer is "654.54 nm".

Explanation:

According to the question,

⇒ [tex]\frac{1}{\lambda}= Rh(\frac{1}{n1^2} -\frac{1}{n2^2} )[/tex]

By substituting the values, we get

       [tex]=1.1\times 10^7(\frac{1}{4} -\frac{1}{9} )[/tex]

       [tex]=1.1\times 10^7(\frac{9-4}{36} )[/tex]

       [tex]=1.1\times 10^7(\frac{5}{36} )[/tex]

       [tex]=654.54\ nm[/tex]

Thus the above is the right solution.

In the graphic, 195 represents the _______.

195 Pt
78

A. Atomic Mass
B. Atomic Number
C. Neutron Number​

Answers

Answer:

ITS ANSWER IS

OPTION B. ATOMIC NUMBER

HI HAVE A NICE DAY

1)Consider the reactions observed when NaOH(aq) and NH3(aq) were added to the solutions containing Zn2 (aq): a)What is the identity of the precipitate formed when the NaOH(aq) and NH3(aq) were added dropwise (limited amounts added)

Answers

Answer:

A white gelatinous precipitate is observed in each case.

Explanation:

Qualitative analysis in chemistry is mostly used to identify the ions present in a sample by adding certain reagents. The observation after adding the reagent often leads to an inference.

When NaOH is added to a solution containing Zn^2+ in drops, a white gelatinous precipitate is observed.

When NH3(aq) is added in drops to a solution containing Zn^2+, a white gelatinous precipitate is also observed.

Too many objects inside a laboratory fume hood can disrupt the airflow and possibly compromise you safety. Which of the following are considered best practices in the use of a laboratory fume hood?

a. Open the sash as much as possible
b. Work at least 25 cm inside the hood
c. Use fast, quick movements to limit your exposure
d. Place objects to one side—work on other side
e. Use a raised along the back of the hood

Answers

Best practices for fume hoods: work 25 cm inside, organize items to one side, use raised ledge; avoid open sash and quick movements.

Laboratory fume hoods must be used safely. Workers should operate at least 25 cm within the hood to preserve ventilation and avoid dangerous chemicals. Place things on one side of the hood to preserve ventilation and prevent clogging.

A raised ledge on the rear of the hood prevents things from falling in and impeding airflow. Avoid fully opening the sash to maintain ventilation and containment. Fast, rapid motions can interrupt airflow, so prevent them. These practises guarantee the fume hood contains harmful compounds, making the lab safer. Therefore, option (B), (D) and (E) are correct.

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A substance is tested and has a pH of 7.0. How would you classify it?

Answers

You can classify it as neutral.

Choose the correct answer:
1.9 × 103 g
1.9 x 106 g
1.9 x 1010 g

Answers

Answer:

A. 1.9 × 103 g

(next one)

Which metric unit would be the best choice to report the result?  

A. kg

Answer:

1. 2

2. 1.9 × 10^3 g

3. kg

Explanation:

Draw the structure of the organic product(s) of the Grignard reaction between methyl benzoate and excess phenylmagnesium bromide, followed by aqueous workup. You do not have to consider stereochemistry. If a compound is formed more than once, add another sketcher and draw it again. Alternatively, you may use the square brackets tool to add stoichiometries greater than one. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner. Separate multiple products using the sign from the drop-down menu.

Answers

Answer:

See explanation and image attached

Explanation:

The product of the Grignard reaction between methyl benzoate and excess phenylmagnesium bromide is triphenyl methanol.

The reaction proceeds by nucleophillic reaction as the carbonyl moiety is attacked. A tetrahedral intermediate is formed. Loss of the -OMe group is accompanied by the attack of the first molecule of PhMgBr.

Attack by a second PhMgBr molecule yields trimethyl phenoxide. Protonation of this specie yields the final product which is obtained by aqueous workup.

The following reaction is not an oxidation-reduction reaction: Fe(s) + 2Hl(aq) --- Fel (aq) + H_(8) Select one: O True O False​

Answers

Explanation:

the reaction is indeed an oxidation reduction reaction

The enthalpy of formation for CO2 (s) and CO2 (g) is: -427.4 KJ/mole and -393.5 KJ/mole, respectively. The sublimation of dry ice is described by CO2 (s) → CO2 (g).

The enthalpy needed to sublime 986 grams of CO2 is:
(a) 181.5 Kcal
(b) 611.7 Kcal
(c) 248.3 Kcal
(d) 146.2 Kcal

Answers

Answer:

a. 181.5 kcal

Explanation:

Step 1: Calculate the enthalpy of the process (ΔH°).

Let's consider the following process.

CO₂(s) → CO₂(g)

We can calculate the enthalpy of the process using the following expression.

ΔH° = ∑ np × ΔH°f(p) - ∑ nr × ΔH°f(r)

ΔH° = 1 mol × ΔH°f(CO₂(g)) - 1 mol × ΔH°f(CO₂(s))

ΔH° = 1 mol × (-393.5 kJ/mol) - 1 mol × (-427.4 kJ/mol) = 33.9 kJ

According to the balanced equation, 33.9 kJ are required to sublime 1 mole of CO₂.

Step 2: Convert 986 g of CO₂ to moles

The molar mass of CO₂ is 44.01 g/mol.

986 g × 1 mol/44.01 g = 22.4 mol

Step 3: Calculate the enthalpy needed to sublime 22.4 moles of CO₂

22.4 mol × 33.9 kJ/1 mol = 759 kJ

We can convert it to Kcal using the conversion factor 1 kcal = 4.184 kJ.

759 kJ × 1 kcal/4.184 kJ = 181.5 kcal

What Volume of silver metal will weigh exactly 2500.0g. The density of silver

Answers

Answer:

cm3 = 2500.0 g / 10.5 g/cm3 = 238 cm3

What process occurs during the corrosion of iron?
Answers

A.
Iron is oxidized.

B.
Iron is reduced.

C.
Iron (III) is oxidized.

D.
Iron (III) is reduced.

Answers

Answer:

A

Explanation:

The iron corrodes so it oxidized

How many moles of HNO3 are needed to prepare 5.7 liters of a 1.64 M solution of HNO3

Answers

We are given:

Volume of Solution: 5.7 Liters

Concentration: 1.64 Molar

Number of moles required:

We know that the formula for concentration (in molar) is:

M = N / V              

where M is the concentration, N is the number of moles, and V is the volume of solution (in L)

plugging the given values in the equation:

1.64 = N / 5.7

N = 1.64 * 5.7            

N = 9.35 moles

Phosphagens are a group of molecules that includes creatine phosphate (in vertebrates), and arginine phosphate, lombricine, and phosphoopheline (in invertebrates). These molecules have similar functions in different organisms.

a. True
b. False

Answers

Answer: True

Explanation:

Phosphagens are high energy storage compounds that are usually found in the tissue of animals.

Based on the question, the molecules have similar functions in different organisms such as the fact that they can accept phosphoryl groups from ATP in a situation where the ATP is in excess. Also, they donate phosphoryl groups to ADP in order for the regeneration of ATP.

Arrange the following compounds in order of increasing reactivity (least reactive first.) to electrophilic aromatic substitution:.

Bromobenzene Nitrobenzene Benzene Phenol

a. Bromobenzene < Nitrobenzene < Benzene < Phenol
b. Nitrobenzene < Bromobenzene < Benzene < Phenol
c. Phenol < Benzene < Bromobenzene < Nitrobenzene
d. Nitrobenzene < Benzene < Bromobenzene < Phenol

Answers

Answer:

Nitrobenzene < Bromobenzene < Benzene < Phenol

Explanation:

Aromatic compounds undergo electrophilic aromatic substitution reaction in the presence of relevant electrophiles. Certain substituents tend to increase or decrease the tendency of an aromatic compound towards electrophilic aromatic substitution reaction.

Substituents that increase the electron density around the ring such as in phenol tends to make the ring more reactive towards electrophilic substitution. Halogens such as bromine has a -I inductive effect as well as a +M mesomeric effect.

However the -I(electron withdrawing effect) of the halogens supersedes the +M electron donation due to mesomeric effect.

Putting all these together, the order of increasing reactivity of the compounds towards electrophilic aromatic substitution is;

Nitrobenzene < Bromobenzene < Benzene < Phenol

Other Questions
President John F. Kennedy and First Lady Jacqueline Kennedy (1961), courtesy of the John F. Kennedy Presidential Library & Museum.Jacqueline Lee Bouvier was born on July 28, 1929, in Southampton, New York. Her father, John, was a wealthy stockbroker on Wall Street whose family had come from France in the early 1800s. Her mother, Janet, had ancestors from Ireland and England. Janet Bouvier was an accomplished rider, and Jackie was only a year old when her mother first put her on a horse. By age 11, she had already won several national championships. In June 1947, Jackie graduated from Miss Porter's School, a boarding school for girls in Connecticut. She continued her education at Vassar College in New York, where she studied history, literature, art, and French. Jacqueline started her first job in the fall of 1951 as the "Inquiring Camera Girl" for the Washington Times-Herald newspaper. Roving around the city, she took pictures of people she encountered, asked them questions on the issues of the day, and wove their answers into her newspaper column. Among those she interviewed for her column was Richard M. Nixon. She also covered the first inauguration of Dwight D. Eisenhower and the coronation of Queen Elizabeth II. During this time, Jacqueline met John F. Kennedy, who was a congressman and soon to be elected a senator from Massachusetts. On September 12, 1953, they married at St. Mary's Church in Newport, Rhode Island. Jacqueline Bouvier Kennedy and John Kennedy talking at their wedding reception, Newport, Rhode Island. Photo Credit Toni FrissellAfter their honeymoon in Mexico, the Kennedys returned to Washington D.C. Early on in their marriage, Senator Kennedy their marriage, Senator Kennedy suffered crippling pain in his back from football and wartime injuries and had two operations. While recovering from surgery, Mrs. Kennedy encouraged him to write a book about several US senators who had risked their careers to fight for the things they believed in. The book, called Profiles in Courage, was awarded the Pulitzer Prize for biography in 1957. That same year, the Kennedys' first child, Caroline, was born. In January 1960, Senator John F. Kennedy announced his candidacy for the presidency of the United States. He began traveling all around the country and Jacqueline often accompanied him.John F. Kennedy leaving the hospital following spinal surgery, with his wife Jacqueline by his side. Photo Credit: DeMarsicoJohn F. Kennedy leaving the hospital following spinal surgery, with his wife Jacqueline by his side. Photo Credit: DeMarsicoOn November 8, 1960, John F. Kennedy beat Republican Richard M. Nixon in a very close race. Two and-a-half weeks later, Mrs. Kennedy gave birth to their second child, John Fitzgerald Kennedy, Jr. On January 20, 1961, John Fitzgerald Kennedy took the oath of the office to become the nation's 35th president. At age 31, Jacqueline Kennedy was the first lady.Select the correct answer.Which details from the passage are emphasized in both the text and images?A. details about Jacqueline Kennedys accomplishments as a riderB. details about Jacqueline Kennedys life inside the White HouseC. details about Jacqueline Kennedys work as a photographerD. details about Jacqueline Kennedys life with John F. Kennedy If the right angle triangle LMN.L=30, MN = 4cm and diagonal LM.Find the LM and LN. At a restaurant, the bill comes to $55. You decide to leave a 12% tip. How much did you leave for the tip? write one to two sentences explaining the meaning of papyrus as it is used in this sentence: These included government officials, doctors, and priests, as well as the scribes who did the actual writing on papyrus and stone. people intering the contest can win a new car =( prize) Write 6.8167 correct to 3 significant figures. O domnio da metrpole portuguesa sobre sua colnia na Amrica submeteu os colonos a condies impostas que, na maioria das vezes, oportunizaram apenas os interesses de Portugal. A explorao excessiva que era realizada por Portugal teve seus reflexos de descontentamento a partir do final do sculo XVII. Neste, ocorreu apenas um movimento de revolta, mas foi ao longo do sculo XVIII que os casos se multiplicaram. Entre os principais movimentos nativistas podemos destacar a Revolta dos Beckman, a Guerra dos Mascates, a Guerra dos Emboabas e a Revolta de Filipe dos Santos. Sobre essas revoltas, pesquise em diferentes fontes e preencha o quadro abaixo com as informaes solicitadas. Give reasons. a. Troposphere is affected maximum by human activities. HELP!!! I need to know if this is Function or not a function. Why did the temperance movement increase during the war A mayor serving in a major metropolitan area receives an internal memorandum indicating personnel at many police stations are single-race. At the time of the report, thirty percent of the police force was black or Hispanic. She immediately calls a press conference and orders transfers of police officers to achieve racial balance across the city. The transferred police officers sue on constitutional grounds. Assuming just these facts, what is the strongest argument that might be advanced by the transferred officers based on constitutional grounds Mr. Denning bought a jacket for $67.50and a tie for $12.50. If a sales tax of 3%was added to the price of his purchase,what was his total bill? why is the Dna molecule able to open up and close? Bryce grew 3 1/2 inches each year for the past 4 years. How many inches total has Bryce grown in the past 4 years? find the quantity whose 15% in 220 THIS IS TIMED I NEED THE ANSWER NOW which best explains how Spain affected the outcome of the revolutionary war HELP ME ASAP!!!two angles are supplementary. one angle is three less than 4 times it's supplement. what are the measures of the two angles? Spain is more to the north than Germany. ???? Slope 0; through (-5, -1)