A chemist titrates 60.0 mL of a 0.1935 M benzoic acid (HC (H5CO2) solution with 0.2088 M KOH solution at 25 °C. Calculate the pH at equivalence. The pKg of benzoic acid is 4.20.

Answers

Answer 1

Answer:

pH at the equivalence point is 8.6

Explanation:

A titulation between a weak acid and a strong base, gives a basic pH at the equivalence point. In the equivalence point, we need to know the volume of base we added, so:

mmoles acid = mmoles of base

60 mL . 0.1935M = 0.2088 M . volume

(60 mL . 0.1935M) /0.2088 M = 55.6 mL of KOH

The neutralization is:

HBz + KOH  ⇄  KBz  +  H₂O

In the equilibrum:

HBz + OH⁻   ⇄  Bz⁻  +  H₂O

mmoles of acid are: 11.61 and mmoles of base are: 11.61

So in the equilibrium we have, 11.61 mmoles of benzoate.

[Bz⁻] = 11.61 mmoles / (volume acid + volume base)

[Bz⁻] = 11.61 mmoles / 60 mL + 55.6 mL = 0.100 M

The conjugate strong base reacts:

  Bz⁻  +  H₂O  ⇄  HBz + OH⁻    Kb

0.1 - x                       x        x

(We don't have pKb, but we can calculate it from pKa)

14 - 4.2 = 9.80 → pKb  → 10⁻⁹'⁸ = 1.58×10⁻¹⁰ → Kb

Kb = [HBz] . [OH⁻] / [Bz⁻]

Kb = x² / (0.1 - x)

As Kb is so small, we can avoid the quadratic equation

Kb =  x² / 0.1 → Kb . 0.1 = x²

√ 1.58×10⁻¹¹ = [OH⁻] = 3.98 ×10⁻⁶ M

From this value, we calculate pOH and afterwards, pH (14 - pOH)

- log [OH⁻] =  pOH → - log 3.98 ×10⁻⁶  = 5.4

pH = 8.6


Related Questions

If an Oxygen atom gains two electrons to form an oxygen ion, it will be
a. more negative by 1.
b. more negative by 2.
c. more positive by 1.
d. more positive by 2.

Answers

the answer is d

i know thiis because i used google hehe

What two processes are occurring in this picture

A.erosion and deposition
B.weathering and deposition
C.weathering and erosion

Answers

Answer:

C. weathering and erosion

Explanation:

what type of chemical reactions is NaOH(ag)+HCI(ag)=NaCL(ag)+H2O​

Answers

Answer:

i hope it helps

Explanation:

This reaction involve an acid (HCl) reacting with a base (NaOH), producing a salt (NaCl) and water. Therefore it's a neutralization reaction.

When comparing the offspring of sexually and asexually reproducing organisms, we would expect the genetic material of the sexually reproducing organism to -


A. Contain fewer mutations

B. Have fewer organisms

C. Be simpler overall

D. How more variation

Answers

Answer:

D more variation.

Explanation:

Asexual reproduction is literally the organism dividing itself into 2, so there is hardly any variation.

The sexual mode of reproduction has been expected to have more variation in the genetic material than the asexual mode of reproduction. Thus, option D is correct.

The asexual mode of replication has been involved with only the parent cell that has been divided into daughter cells with the meiosis and mitosis process.

The sexual mode of reproduction has been accomplished by the fusion of male and female gametes.

The chances of variations or mutations have been higher in the sexual mode of reproduction as two cells fuse together for the formation of the offspring. In the asexual mode of reproduction, the same cell has been divided into the daughter cell, thus the chances of variations have been lower.

Thus, the sexual mode of reproduction has been expected to have more variation in the genetic material than the asexual mode of reproduction. Thus, option D is correct.

For more information about the mode of reproduction, refer to the link:

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What do you think the study of chemistry might be about? Thanks for everyone’s help

Answers

Answer:

Explanation:

chemistry lol

50 POINTS
Which is a mixture whose solute particles are individual ions or molecules?

solvent
suspension
colloid
solution

Answers

Answer:

A mixture whose components are soluble in each other. ... a solution that has water as its solvent; most have an ionic substance as the solute, may contain a liquid ... The suspensions of particles larger than individual ions or molecules, but the ... This effect is used to determine whether a mixture is a true solution or a colloid.

process of solute particles being surrounded by water molecules arranged in a ... solution. homogeneous mixture consisting of a solute dissolved into a solvent. ... apart from the crystal, the individual ions are then surrounded by solvent particles in a ... are intermediate in size between those of a solution and a suspension.

A suspension is a heterogeneous mixture in which some of the particles ... The particles in a suspension are far larger than those of a solution, so gravity is … ... Particle size: 0.01-1nm; atoms, ions or molecules, Particle size: ... solutions because the individual dispersed particles of a colloid cannot be seen.

Explanation:

Which TWO statements describe the ocean floor giving brainliest pls

Answers

Answer:

i think that it is. d and b, im not completely sure but ik d is included

Explanation:

Answer:

think b and a

Explanation:

Which should have the highest vapor pressure at a given temperature?
A CH4
B C2H6
C C4H10
D they should all be the same

Answers

C ansnsmenemwmwmwmwmemene

A mixture contains NaHCO3 together with unreactive components. A 1.54 g sample of the mixture reacts with HA to produce 0.561 g of CO2. What is the percent by mass of NaHCO3 in the original mixture

Answers

Answer:

69.55 (w/w) %

Explanation:

When NaHCO3 reacts with an acid HA, the reaction that occurs is:

NaHCO3 + HA → H2O + NaA + CO2

Where 1 mole of NaHCO3 produce 1 mole of CO2

Thus, we need to convert the mass of CO2 to moles using its molar mass (44g/mol). Then, based on the chemical equation, moles of CO2 produced are equal to moles of NaHCO3 in the mixture. With its molar mass -84g/mol- we can find the mass of NaHCO3 and mass percent:

Moles CO2:

0.561g * (1mol / 44g) = 0.01275 moles CO2 = Moles NaHCO3.

Mass NaHCO3:

0.01275 moles * (84g/mol) = 1.071g NaHCO3

Mass percent:

1.071g NaHCO3 / 1.54g sample * 100

69.55 (w/w) %

How many grams of water (s=1.00 cal/g C) will release 1367 J of heat when cooled from 45.2 C to 36.2 C?
a) 42 g
b) 36 g
c) 31 g
d) 28 g

Answers

Answer:

Mass of water  = 36 g

Explanation:

Given data:

Amount of energy released = 1367 J = 1367/4.184 = 327 cal

Initial temperature = 45.2 °C

Final temperature = 36.2 °C

Amount of water = ?

Solution:

Specific heat capacity of water is 1 cal/g.°C

Formula:

Q = m.c. ΔT

Q = amount of heat absorbed or released

m = mass of given substance

c = specific heat capacity of substance

ΔT = change in temperature

ΔT = 36.2 °C -  45.2 °C

ΔT = -9°C

-327 cal = m×1 cal/g.°C ×  -9°C

m = -327 cal/-9cal/g

m = 36 g

Which of the following is a chemical change?
A. Boiling water using fire
B. Breathing in oxygen and breathing out carbon dioxide
C. Ripping a piece of paper in half
D. Melting gold to make jewelry

Answers

B is a physical change, A involves no chemical change, C is a physical change. So your answer is D.

How many dots would the electron dot structure for Be have?

Answers

Answer:

it has 2 valence electrons

Explanation:

i hope this helps

A Venn diagram is used to compare and contrast different topics. The items that are unique to each topic are represented in the separate sections of the circles, and the items that are common to both topics are represented in the center overlapping sections. Harlow creates this Venn diagram comparing and contrasting endothermic and exothermic processes. Two overlapping circles are labeled on the left endothermic and on the right exothermic. In the left circle are labels requires energy and examples. In the right circle are labels releases energy and examples. In the overlap is the label involve energy. What can be added to the Examples section of each circle? Endothermic: ice melting into water, and a heat pack becoming warm Exothermic: a glow stick glowing, and fireworks exploding Endothermic: ice melting into water, and an instant ice pack turning cold Exothermic: fireworks exploding, and gasoline burning Endothermic: a glow stick glowing, and a heat pack becoming warm Exothermic: an instant ice pack turning cold, and ice melting into water Endothermic: gasoline burning, and an instant ice pack turning cold Exothermic: ice melting into water, and an instant ice pack turning cold

Answers

Answer:

Endothermic: ice melting into water, and an instant ice pack turning cold  Explanation:

Answer:

B is the correct answer lol its the only logical one

Explanation:

If you start with 1.5 moles of H2O, how many moles of H4SiO4 do you make?

Answers

Answer:

0.75moles of  H₄SiO₄

Explanation:

Given parameters:

Number of moles of H₂O  = 1.5moles

Unknown:

Number of moles of H₄SiO₄  = ?

Solution:

To solve this problem, we need to write the reaction equation first;

            SiO₂  +  2H₂O  →   H₄SiO₄

From the balanced reaction equation:

             2 moles of water will produce 1 mole of  H₄SiO₄

    So     1.5 moles of water will produce [tex]\frac{1.5}{2}[/tex]   = 0.75moles of  H₄SiO₄

the increase in atomic radius as you go down the periodic table is caused by?​

Answers

Answer: The number of energy levels increases as you move down a group as the number of electrons increases. Each subsequent energy level is further from the nucleus than the last. Therefore, the atomic radius increases as the group and energy levels increase.

Which term describes this molecular shape?

A. Trigonal pyramidal
B. Trigonal planar
C. Tetrahedral
D. Linear

Answers

Answer: Trigonal Pyrimidal

Explanation: Just took test

How many unshared electrons are found in the lewis dot structure of Carbon Dioxide or CO2?

Answers

There are 4 lone pairs of electrons present in the carbon dioxide molecule

PLEASE MARK ME AS BRAINLIEST

Answer:

Explanation:

Carbon dioxide, CO2

Each oxygen contributes 2 electrons - 1 for each bond. That means there are a total of 8 electrons around the carbon, in 4 pairs. Because there are 4 bonds, these are all bond pairs.

Which of the period 2 homonuclear diatomic molecules are predicted to be paramagnetic?

Answers

O2
Therefore, among period 2 homonuclear diatomic molecules, only O2 is paramagnetic.

What is the pH at the equivalence point of the titration of 50.0 mL of 0.300 M NH3(aq) with 0.150 M HCl(aq)?

Answers

Answer:

pH = 5.19, at the equivalence point

Explanation:

This is titration of a weak base and a strong acid. pH in the equivalence point will be acid. To determine this pH, we know that in in the equivalence point:

mmoles base = mmoles of base

50 mL  . 0.3M = 0.150 M . Volume of acid

Volume of acid = (50 . 0.3)/ 0.15 → 100 mL

Total volume of equivalence point is 50 mL + 150 mL = 200 mL

Neutralization reaction is:

NH₃ + HCl → NH₄Cl

NH₃ +  H₃O⁺ ⇄  NH₄⁺  +  H₂O

15          15

0           0            15

Ammonia's Kb = 1.8×10⁻⁵

In the equivalence point, we have only ammonium, beacuse all the amonia reacted to the protons. Let's make the equilibrium

      NH₄⁺  +  H₂O  ⇄  NH₃  +  H₃O⁺      Ka

I:      15            -             -            -

Eq:  15-x                        x           x

Ka = 1×10⁻¹⁴ / Kb → 5.55×10⁻¹⁰

[NH₄⁺] = 15 mmoles / 200 mL = 0.075 M

In the equilibrium, we can avoid the 15 - x, because Ka is soo small.

Expression for Ka is [ NH₃ ] .  [H₃O⁺] /  [NH₄⁺] = 5.55×10⁻¹⁰

[H₃O⁺] = √(5.55×10⁻¹⁰ . 0.075)

[H₃O⁺] =  6.45×10⁻⁶

- log [H₃O⁺] =  pH → 5.19

In an ionic bond, what do the electrons do in order to form the bond?

1. Share
2. Transfer

Answers

Answer:

Transfer

Explanation:

Sharing happens at covalent bond

Transfer happens at ionic bond

This why we say to ion because they give electron get positive or take electron and negative

The formation of an ionic bond involves the what?

Answers

Answer is: transfer of electrons.
Ionic bond is the electrostatic attraction between oppositely charged ions.
For example, compound magnesium chloride (MgCl₂) has ionic bond.
Magnesium (Mg) transfers two electrons, became positive cation, to chlorine (Cl), which became negative anion.
Magnesium is metal from group 2 and chlorine is nonmetal from group 17 of the Periodic table.

Which of the following is not a reason why chemical bonds are important

Answers

B. Building and breaking bonds are part of the energy cycle

Answer:

I only see B as a answer

Explanation:

how many atoms of oxygen are in a molecule of nitroglycerin

Answers

Answer:

i think there are 3 carbon and 5 hydrogen

Explanation:

There are 9 atoms of Oxygen in a molecule of nitroglycerin.

What is Nitroglycerin?

Nitroglycerin is also called Trinitroglycerin, It is an oily, thick, colorless liquid.

A vasodilator, nitroglycerin is generally used to relieve anginal chest pain. Currently, the FDA has approved it for the acute prophylaxis of angina pectoris owing to coronary artery disease as well as the acute alleviation of an episode.

It is used in manufacturing explosives.

The molecular formula of Nitroglycerin is C₃H₅N₃O₉

The chemical formula is 1,2,3-trinitroxypropane.

A molecular formula shows the number of atoms present in the compound.

The number of atoms of Carbon present is 3.

The number of atoms of Hydrogen present is 5.

The number of atoms of Nitrogen present is 3.

The number of atoms of Oxygen present is 9.

So, the total number of atoms of Oxygen present is 9.

To know more about Nitroglycerin

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Methane (CH4) is the main component of marsh gas. Heating methane in the presence of sulfur produces carbon disulfide and hydrogen sulfide as the only products. (a) Write the balanced chemical equation for the reaction of methane and sulfur. (Use the lowest possible coefficients. Include states of matter under SATP conditions in your answer.)(b) Calculate the theoretical yield of carbon disulfide when g of methane is reacted with an equal mass of sulfur.

Answers

Answer:

71.25 g

Explanation:

Methane + Sulfur = Carbon Disulfide + Hydrogen Sulfide

The equation is given as;

CH4 + S --> CS2 + H2S

Upon balancing, we have;

CH4(g) + 4S(s) → CS2(l) + 2H2S(g)

Theoretical yield of carbon disulphide;

Equal masses of 120g

The limiting reactant is sulphur It determines how much of the product is formed.

From the equation;

4 mol of S produces 1 mol of CS2

upon converting to masses using; Mass = number of mol * Molar mass

4 mol of S = 4 * 32

1 mol of CS2 = 76g

128g of S produces 76g of C2, 120g would produce ?

128 = 76

120 = x

x = 120 * 76 / 128

x = 71.25g

(a).  The balanced chemical reaction will be:

[tex]\rm CH_4\;(g)+\;4\;S\;(s)\rightarrow\;CS_2\;(l)+\;2\;H_2S\;(g)[/tex]

(b). 120 grams of sulfur will produce 71.25 grams of carbon disulfide.

The heating of methane in the presence of sulfur can be given by:

[tex]\rm CH_4\;+\;S\;\rightarrow\;CS_2\;+\;H_2S[/tex]

(a). The lowest possible coefficients have been used to balance the number of elements on both sides i.e. reactant and the product.

[tex]\rm CH_4\;+\;4\;S\;\rightarrow\;CS_2\;+\;2\;H_2S[/tex]

The state of the elements has also been mentioned in the chemical equation. The state of methane is gas, sulfur is solid, carbon disulfide is liquid and hydrogen disulfide is gas.

Thus the balanced chemical reaction will be:

[tex]\rm CH_4\;(g)+\;4\;S\;(s)\rightarrow\;CS_2\;(l)+\;2\;H_2S\;(g)[/tex]

(b). When 120 grams of sulfur reacts, the yield of carbon disulfide will be:

From the balanced equation, 4 moles of sulfur will give 1 mole of carbon disulfide.

4 moles of Sulfur = mole [tex]\times[/tex] molecular weight

4 moles of Sulfur = 4 [tex]\times[/tex] 32

4 moles of Sulfur = 128 grams.

1 mole of carbon disulfide = 76 grams.

So, 128 grams of sulfur produces, 76 grams of carbon disulfide.

Thus, 120 grams of sulfur will produce = [tex]\rm \dfrac{76}{128}\;\times\;120[/tex] grams Carbon disulfide

120 grams of sulfur will produce = 71.25 grams of Carbon disulfide.

Thus, 120 grams of sulfur will produce 71.25 grams of carbon disulfide.

For more information about a chemical reaction, refer to the link:

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What is MS-Word?MS Word Ki Hai hardware software Ki Hai ​

Answers

Answer:

Ms word is a type of application that is used to make your work more easier nd attractive.

Explanation:

For ex- you can draw a line,you can highlight your text,make your text bold and you can also increase and decrease the font size.

someone please help me js fill in the blanks

Answers

Answer:

Valence electrons are found on the outer shell of an atom and react with other atoms. For most atoms, the number is 8 electrons to make a compound stable. Elements in Group 1 have 1 valence electron(s) and are most reactive. Elements in group 18 have 8 valence electrons, making them "stable" and not reactive.

SOMEONE PLEASE HELP ME

Answers

Answer:

1.7

Explanation:

4.52/2.6 = 1.738461538, which can be simplified to 1.7

Answer:

1.7

Explanation:

What type of reaction is NaCI + AgNO3 to NaNO3 + AgCI

Answers

Answer:

Double displacement reaction

Explanation:

The reaction shown is a double displacement or double decomposition reaction. It is also called a metathesis.

In a double displacement reaction, there is an actual exchange of partners. One the partners are exchanged new products are formed. The reaction is driven by the formation of a precipitate. Also, some times water or non-ionizing compound forms. There is also a liberation of gaseous products.

Find the enthalpy for a constant pressure calorimetry reaction where the reaction occurs in a 250ml aqueous solution. The temperature changes from 25.0c to 26.1 c

Assume that cool = 4.18j/gt

Answers

Answer:

[tex]\Delta H=1149.5J[/tex]

Explanation:

Hello!

In this case, since the calorimeter contains a solution for which the specific heat is 4.18 J/g°C, which is equal to that of the water, we can also notice that the density is 1.00 g/mL and therefore the present mass is 250 g. In such a way, we compute the enthalpy change as shown below:

[tex]\Delta H=mC\Delta T[/tex]

Thus, by plugging in the mass, specific heat and temperature change, we obtain:

[tex]\Delta H=250g*4.18\frac{J}{g\°C}(26.1\°C-25.0\°C)\\\\\Delta H=1149.5J[/tex]

Best regards!

How red blood cells different to animal cells

Answers

Answer:

By contrast, the red blood cells of mammals lack nuclei and other internal structures found in most animal cells. This simplification allows mammal red blood cells to carry more gas-transporting proteins and to squeeze through smaller blood vessels.

Explanation:

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